Carl Gassner
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Carl Gassner is a German physician (17 November 1855 in
Mainz Mainz () is the capital and largest city of Rhineland-Palatinate, Germany. Mainz is on the left bank of the Rhine, opposite to the place that the Main joins the Rhine. Downstream of the confluence, the Rhine flows to the north-west, with Ma ...
; † 31 January 1942), scientist and inventor, better known to have contributed to improve the Leclanché cell and to have fostered the development of the first
dry cell upLine art drawing of a dry cell: 1. brass cap, 2. plastic seal, 3. expansion space, 4. porous cardboard, 5. zinc can, 6. carbon rod, 7. chemical mixture A dry cell is a type of electric battery, commonly used for portable electrical devices. Unl ...
, also known as the
zinc–carbon battery A zinc–carbon battery (or carbon zinc battery in U.S. English) is a dry cell primary battery that provides direct electric current from the electrochemical reaction between zinc and manganese dioxide (MnO2) in the presence of an electrolyte. I ...
, less likely to break or leak and that could be effectively industrially produced at large scale.


Life

Gassner studied the medicine at the
University of Strasbourg The University of Strasbourg (french: Université de Strasbourg, Unistra) is a public research university located in Strasbourg, Alsace, France, with over 52,000 students and 3,300 researchers. The French university traces its history to the ea ...
and then practiced in
Mainz Mainz () is the capital and largest city of Rhineland-Palatinate, Germany. Mainz is on the left bank of the Rhine, opposite to the place that the Main joins the Rhine. Downstream of the confluence, the Rhine flows to the north-west, with Ma ...
(Germany) as a specialist in diseases of the eyes and ears. He also conducted experiments in physics and chemistry at the Balbach watchmaking industry.


Invention of dry cell

In 1880, most of the door bells operated with a wet Leclanché cell containing an aqueous electrolyte solution which often dried out, rendering the cell unusable. To remediate this inconvenience, in 1876, Georges Leclanché started to jellify the electrolyte of his cell by adding
starch Starch or amylum is a polymeric carbohydrate consisting of numerous glucose units joined by glycosidic bonds. This polysaccharide is produced by most green plants for energy storage. Worldwide, it is the most common carbohydrate in human die ...
to the ammonium chloride, making also his cell more portable. In 1885, Gassner also decided to modify the Leclanché cell by immobilising the liquid
electrolyte An electrolyte is a medium containing ions that is electrically conducting through the movement of those ions, but not conducting electrons. This includes most soluble salts, acids, and bases dissolved in a polar solvent, such as water. Upon ...
in
plaster of Paris Plaster is a building material used for the protective or decorative coating of walls and ceilings and for moulding and casting decorative elements. In English, "plaster" usually means a material used for the interiors of buildings, while "re ...
used as a porous binder, to which he added
hydrophilic A hydrophile is a molecule or other molecular entity that is attracted to water molecules and tends to be dissolved by water.Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon'' Oxford: Clarendon Press. In contrast, hydrophobes are n ...
chemicals and
zinc chloride Zinc chloride is the name of inorganic chemical compounds with the formula ZnCl2 and its hydrates. Zinc chlorides, of which nine crystalline forms are known, are colorless or white, and are highly soluble in water. This salt is hygroscopic ...
. The purpose of the addition of ZnCl2 was to limit the
corrosion Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engi ...
rate of the zinc
anode An anode is an electrode of a polarized electrical device through which conventional current enters the device. This contrasts with a cathode, an electrode of the device through which conventional current leaves the device. A common mnemonic is ...
when the cell is not used and so to extend the
service life A product's service life is its period of use in service. Several related terms describe more precisely a product's life, from the point of manufacture, storage, and distribution, and eventual use. Service life has been defined as "a product's ...
of the cell. On 8 April 1886 he obtained a patent in Germany, and on 15 November 1887 in the United States. He also obtained different patents in
Austria-Hungary Austria-Hungary, often referred to as the Austro-Hungarian Empire,, the Dual Monarchy, or Austria, was a constitutional monarchy and great power in Central Europe between 1867 and 1918. It was formed with the Austro-Hungarian Compromise of ...
,
Belgium Belgium, ; french: Belgique ; german: Belgien officially the Kingdom of Belgium, is a country in Northwestern Europe. The country is bordered by the Netherlands to the north, Germany to the east, Luxembourg to the southeast, France to ...
, France and England. His dry cell became known in 1890, when a friend of his shopkeeper asked him for help because the door bell did not work. Later also the other dealers wanted his dry cell. Subsequently, the director of the
Erfurt Erfurt () is the capital and largest city in the Central German state of Thuringia. It is located in the wide valley of the Gera river (progression: ), in the southern part of the Thuringian Basin, north of the Thuringian Forest. It sits in ...
post-office ordered 100,000 batteries, forcing Gassner to establish a factory in
Frankfurt Frankfurt, officially Frankfurt am Main (; Hessian: , " Frank ford on the Main"), is the most populous city in the German state of Hesse. Its 791,000 inhabitants as of 2022 make it the fifth-most populous city in Germany. Located on it ...
. He could have earned millions of marks, but for peace he renounced all the rights of the Frankfurt company and the production was interrupted. He is buried in the main cemetery of Mainz.


Zinc-carbon battery

The global chemical reaction occurring in the zinc-carbon battery is the following: \mathsf


See also

*
History of the battery Batteries provided the primary source of electricity before the development of electric generators and electrical grids around the end of the 19th century. Successive improvements in battery technology facilitated major electrical advances, f ...
* Georges Leclanché * Leclanché cell * Zinc-carbon battery


References


External links

* * * * * * {{DEFAULTSORT:Gassner, Carl Battery inventors 19th-century German inventors 1855 births 1942 deaths Physicians from Mainz 19th-century German physicians